منابع مشابه
Triplet energies of pi-conjugated polymers.
Using pulse radiolysis and triplet energy transfer has enabled us to measure the triplet energies in a broad range of different pi-conjugated polymers. In all cases we find that the 1 (3)B(u) is of order 0.6 to 1 eV below the 1 (1)B(u), indicative of localized triplet states with strong electron-electron correlation. We also observe that the 1 (1)A(g)-1 (3)B(u) gap decreases linearly as the 1 (...
متن کاملGroundstate dispersion interaction between pi-conjugated polymers.
The line-dipole approximation is used to investigate the scaling of the groundstate dispersion interaction, EW, between parallel conjugated polymers of length L and transverse separation D. Both a second-order perturbation theory calculation using the Mott-Wannier exciton model of excited states and a semiclassical analysis of distributed dipoles indicate that at L approximately D there is a cr...
متن کاملPatterning of Highly Conductive Conjugated Polymers for Actuator Fabrication
Trilayer polypyrrole microactuators that can operate in air have previously been developed. They consist of two outer layers of the electroactive polymer polypyrrole (PPy) and one inner layer of a porous poly(vinylidene flouride) (PVDF) membrane containing a liquid electrolyte. The two outer layers of PPy are each connected with gold electrodes and separated by the porous PVDF membrane. This mi...
متن کاملLow-Dimensional Conduction Mechanisms in Highly Conductive and Transparent Conjugated Polymers.
Electronic conduction in conjugated polymers is of emerging technological interest for high-performance optoelectronic and thermoelectric devices. A completely new aspect and understanding of the conduction mechanism on conducting polymers is introduced, allowing the applicability of materials to be optimized. The charge-transport mechanism is explained by direct experimental evidence with a ve...
متن کاملChiral -conjugated organoboron polymers*
A novel π-conjugated organoboron polymer with a chiral side chain was prepared by way of hydroboration polymerization between an optically active diyne monomer and triisopropylphenylborane. The achiral analog of this organoboron polymer was also prepared as reference material. Optical properties and optical activity were investigated by UV–vis absorption, fluorescence emission, and circular dic...
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ژورنال
عنوان ژورنال: NIPPON GOMU KYOKAISHI
سال: 2008
ISSN: 1884-0442,0029-022X
DOI: 10.2324/gomu.81.80